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Hexakis (1, 3-dithio-2-ylidene) cyclohexane with two different conformations of the six-membered ring

T Sugimoto, Y Misaki, T Kajita, Z Yoshida…

文献索引:Sugimoto,T.; Misaki,Y.; Kajita,T. Journal of the American Chemical Society, 1987 , vol. 109, p. 4106

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被引用次数: 39

摘要

1987, 109, 4106-4107 the other transition-metal complexes. 2 However, it was quite unknown whether cyclooligomerization of cumulenes bearing sulfur substituents occurs by a transition-metal complex catalyst. Recently we succeeded in the synthesis of tetrakis (1, 3- dithiol-2-ylidene) cyclobutane, a promising electron donor for organic metals, by Ni (0)- catalyzed reductive cyclodimerization of 2, 2'-(1, 2-dibromoethanediylidene) bis (1, 3- ...