Syntheses, with the aid of (4??pyridyl)??magnesium chloride, of 4??lithiopyridine and of 3??lithioquinoline

JP Wibaut, LG Heeringa

文献索引：Wibaut; Heeringa Recueil des Travaux Chimiques des Pays-Bas, 1955 , vol. 74, p. 1003,1015

全文：HTML全文

被引用次数: 39

摘要

J. P. WIBAUT and LG HEERINGA * ) (Laboratory for Organic Chemistry of the Municipal University of Amsterdam). 99th Communication on Derivatives of Pyridine and Quinoline. ... 4-Chloropyridine can be converted for about 70% into a complex magnesium compound, which reacts in the manner of a Grignad compound with aldehydes or ketones, forming (4-pyridyl) -carbinols; with orthoformic ester, (4-pyridyl)-methanal-acetal is formed. The reaction of 4-lithiopyridine with ...