Abstract Cycloaddition of dichloroketene to N, N-disubstituted 6-aminomethylene-5, 6- dihydro-2-phenylbenzothiazol-7-(4H) ones gave in good yield N, N-disubstituted 4-amino-3, 3-dichloro-3, 4, 5, 6-tetrahydro-8-phenyl-2H-pyrano [3, 2-g] benzothiazol-2-ones II, which are derivatives of the new heterocyclic system 2H-pyrano [3, 2-g] benzothiazole.