Autoxidation of N-alkylamides. Part I. N-Acylamides as oxidation products

MV Lock, BF Sagar

文献索引：Lock,M.V.; Sagar,B.F. Journal of the Chemical Society [Section] B: Physical Organic, 1966 , p. 690 - 696

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被引用次数: 44

摘要

Products of the thermal and photosensitised autoxidation of N-alkyl-and NN-dialkyl-amides have been identified. Nn-Alkylamides yield principally N-acylamides, primary amides, and N- formylamides, as a result of initial abstraction of a hydrogen atom from the carbon adjacent to nitrogen. Formation of N-formylamides, and of N-acylamides from Ns-alkylamides, involves C (1)–C (2) bond scission in an N-alkyl group. Oxidation of NN-dialkylamides ...