Synthesis, Structure, and Catalytic Activity of Bimetallic PtII–IrIII Complexes Bridged by Cyclooctane??1, 2??dithiolato Ligands

…, M Sakashita, C Komatsubara, A Ishii

文献索引：Nakata, Norio; Sakashita, Masahiro; Komatsubara, Chizuru; Ishii, Akihiko European Journal of Inorganic Chemistry, 2010 , # 3 p. 447 - 453

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被引用次数: 6

摘要

Abstract Cationic Pt II–Ir III heterobimetallic complexes bridged by cyclooctane-1, 2-dithiolato ligands [(PPh 3) 2 Pt (μ 2-SRS) IrCl (η 5-Cp*)][SbF 6][R= cis-C 8 H 14 (5), trans-C 8 H 14 (6), Cp*= C 5 Me 5] were synthesized by reaction of (cyclooctane-1, 2-dithiolato) Pt II complexes [Pt (SRS)(PPh 3) 2][R= cis-C 8 H 14 (3), trans-C 8 H 14 (4)] with [IrCl (μ-Cl)(η 5-Cp*)] 2 in thf in the presence of AgSbF 6. The structures of complexes 5 and 6 were fully characterized ...