Atmospheric chemistry of benzene oxide/oxepin

B Klotz, I Barnes, KH Becker, BT Golding

文献索引：Klotz, Bjoern; Barnes, Ian; Becker, Karl H.; Golding, Bernard T. Journal of the Chemical Society - Faraday Transactions, 1997 , vol. 93, # 8 p. 1507 - 1516

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被引用次数: 77

摘要

The atmospheric chemistry of benzene oxide/oxepin, a possible intermediate in the atmospheric oxidation of aromatic hydrocarbons, has been investigated in a large volume photoreactor at 298 K and atmospheric pressure using in situ FTIR spectroscopy for the analysis. Rate coefficients of (10.0±0.4)× 10-11 and (9.2±0.3)× 10-12 cm 3 molecule-1 s-1 have been determined for the reaction of benzene oxide/oxepin with OH and NO 3 ...