Thermolysis of pentamethyldisilane and 1 H-heptamethyltrisilane

H Sakurai, A Hosomi, M Kumada

文献索引：Sakurai,H. et al. Journal of the Chemical Society [Section] D: Chemical Communications, 1969 , p. 4 - 5

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摘要

PREVIOUSLY, u7e have described1 that hexamethyldisilane undergoes almost quantitative rearrangement to trimethyl-(dimethylsilylmethy1) silane by thermolysis at 400-450" in a sealed tube; this thermolysis differs considerably from the pyrolysis of hexamethyldisilane at low pressure. 2 Here we report the thermal reactions of polysilane carried out in a sealed tube. When pentamethyldisilane (I) was thermolysed at 300-325" for 15 hr. in a sealed ...