Journal of the American Chemical Society

Reaction of organoboranes with dichloroacetonitrile under the influence of potassium 2, 6-di-tert-butylphenoxide. A convenient general procedure for the preparation …

H Nambu, HC Brown

文献索引：Nambu,H.; Brown,H.C. Journal of the American Chemical Society, 1970 , vol. 92, p. 5790 - 5791

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被引用次数: 11

摘要

We previously reported that the reaction of simple organoboranes or B-alkyl-9-borabicyclo [3.3. l] nonanes4 with ethyl mono-and dihaloacetates, in the presence grouping in such reaction^.^ Accordingly, we undertook a study of the alkylation of dichloroacetonitrile. Monoalkylation of dichloroacetonitrile was first studied. A procedure which involves the addition of potassium tert-butoxide in tetrahydrofuran to an equimolar mixture of an ...