Journal of the American Chemical Society

THE MECHANISM OF REACTION BETWEEN THIONYLANILINE AND ORGANOMAGNESIUM HALIDES

H Gilman, HL Morris

文献索引：Gilman; Morris Journal of the American Chemical Society, 1926 , vol. 48, p. 2403

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被引用次数: 18

摘要

Thionylamines (RS= S= O) are related structurally to ketenes (R% C= C= O) isocyanates (RN= C= O) and isothiocyanates (RX== C= S). These different classes of compounds have a pair of terminal cumulated unsaturated groups and take part in a number of reactions in common. It has been proved that the ketenes12 isocyanates3 and isothi~ cyanates~ react under ordinary conditions with but one molecular proportion of RMgX compound. Addition ...