Raman and infrared spectra, quantum chemical calculations, conformations and spectral assignments of 1-chloro-1-methyl-1-silacyclohexane

P Klaeboe, CJ Nielsen, A Horn, GA Guirgis…

文献索引：Klaeboe, Peter; Nielsen, Claus J.; Horn, Anne; Guirgis, Gamil A.; Overby, Jason S.; Aleksa, Valdemaras Journal of Molecular Structure, 2013 , vol. 1047, p. 282 - 291

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被引用次数: 8

摘要

A 1, 1-disubstituted silacyclohexane, 1-chloro-1-methyl-1-silacyclohexane, C5H10SiClCH3, was synthesized and studied by infrared and Raman spectroscopy. The infrared spectra of the vapor and liquid were recorded at ambient temperature and the solid sample investigated at 78K. Negligible spectral changes ocurred at 78K compared with the fluid state, but after annealing to ca. 165K an apparent crystal was formed. Raman spectra of ...