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The Journal of Organic Chemistry

Nitrolysis of dialkyl tert-butylamines

DA Cichra, HG Adolph

文献索引:Cichra, Dorothy A.; Adolph, Horst G. Journal of Organic Chemistry, 1982 , vol. 47, # 12 p. 2474 - 2476

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被引用次数: 58

摘要

and-amines7 suggested that the tert-butyl group might be particularly useful in this regard. We now report on the nitrolysis of N-tert-butylamines containing (mostly nitroalkyl) substituents of varying electron demand. The amines 1-3 used as model compounds in the present work were obtained by the Mannich condensation of tert-butylamine with the appropriate nitroalkanes (eq 1-3),