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Reactions of isopropyl methylphosphonofluoridate with substituted phenols. II

J Epstein, HO Michel, DH Rosenblatt…

文献索引:Epstein,J. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 4959 - 4963

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被引用次数: 27

摘要

A previous study on the reactivity of isopropyl methylphosphonofluoridate (GB) with various phenolic anions indicated that the incorporation of a cationic site into the phenolic nucleus increased the reactivity of the anion relative to its basic strength. Further studies have been carried out on this" charge" effect, the classes of compounds investigated and reported in this paper being mono-and bisdimethylaminomethylphenols,-catechols, and-pyrogallols. ...