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Physical properties and various reactions of thionitrites and related substances.

S Oae, K Shinhama, K Fujimori, YH Kim

文献索引:Oae, Shigeru; Shinhama, Koichi; Fujimori, Ken; Kim, Yong Hae Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 3 p. 775 - 784

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被引用次数: 56

摘要

Several new sulfonyl or sulfonyl derivativives, thionitrates (RSNO 2), sulfonyl nitrites (RSO 2 NO), were successfully isolated by treating corresponding thiols and sulfinic acids with dinitrogen tetraoxide (N 2 O 4). Spectroscopic data of both stable and many rather unstable compounds were determined and compared with those of corresponding alkyl nitrites (RONO) or alkyl nitrates (RONO 2). Chemical reactivities of these uncommon, novel S- ...