Inter??and Intramolecular Hydroamination of Unactivated Alkenes Catalysed by a Combination of Copper and Silver Salts: The Unveiling of a Brønstedt Acid Catalysis

…, P Roussel, F Agbossou??Niedercorn

文献索引：Michon, Christophe; Medina, Florian; Capet, Frederic; Roussel, Pascal; Agbossou-Niedercorn, Francine Advanced Synthesis and Catalysis, 2010 , vol. 352, # 18 p. 3293 - 3305

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被引用次数: 36

摘要

Abstract The combined use of a copper halide, a silver salt and a phosphane ligand was applied for the catalysis of inter-and intramolecular hydroamination of alkenes. The reactions of unactivated olefins with nitrogen substrates were investigated. Mechanistic investigations demonstrated that the catalytic system generated a Brønsted acid which appeared to be the prominent catalytic species.