Tris (acetylacetonato) rhodium (III)??Catalyzed α??Alkylation of Ketones, β??Alkylation of Secondary Alcohols and Alkylation of Amines with Primary Alcohols

…, GM Reddy, H Maheswaran, ML Kantam

文献索引：Satyanarayana, Ponnam; Reddy, Ganapam Manohar; Maheswaran, Hariharasharma; Kantam, Mannepalli Lakshmi Advanced Synthesis and Catalysis, 2013 , vol. 355, # 9 p. 1859 - 1867

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被引用次数: 26

摘要

Abstract The tris (acetylacetonato) rhodium (III) catalyst is shown to be a versatile catalyst in the presence of DABCO (1, 4-diazabicyclo [2.2. 2] octane) as ligand for the α-alkylation of ketones followed by transfer hydrogenation, for the one-pot β-alkylation of secondary alcohols with primary alcohols and for the alkylation of aromatic amines in the presence of an inorganic base in toluene.