Controlled oxidations of benzo [a] pyrene

E Lee-Ruff…

文献索引：Lee-Ruff, E.; Kazarians-Moghaddam, H.; Katz, M. Canadian Journal of Chemistry, 1986 , vol. 64, p. 1297 - 1303

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被引用次数: 27

摘要

The four diones derived from benzo [a] pyrene oxidation have been characterized by high- field nuclear magnetic resonance techniques including 2-D COSY and selective nuclear Overhauser enhancement. All the proton chemical shifts for these four quinones have been uneqivocally assigned. The direct photoxidation of benzo [a] pyrene gives a product distribution very similar to the TPP photosensitized oxygenation, suggesting singlet ...