Facile synthesis of 6-aryl-3-pyridyl-1, 2, 4-triazines as a key step toward highly fluorescent 5-substituted bipyridines and their Zn (II) and Ru (II) complexes
…, DS Kopchuk, MM Ustinova, B König, DN Kozhevnikov
文献索引：Kozhevnikov, Valery N.; Shabunina, Olga V.; Kopchuk, Dmitry S.; Ustinova, Maria M.; Koenig, Burkhard; Kozhevnikov, Dmitry N. Tetrahedron, 2008 , vol. 64, # 37 p. 8963 - 8973
A wide series of substituted bipyridines were obtained through the synthesis of 1, 2, 4- triazines and their aza Diels–Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn (II) and Ru (II) complexes. Some of substituted bipyridines exhibit 'off–on'fluorescence response toward Zn2+ cations.
