Synthesis of ketone and alcohol derivatives of methylene-bridged polyarenes, potentially new classes of active metabolites of carcinogenic hydrocarbons

RG Harvey, E Abu-Shqara…

文献索引：Harvey, Ronald G.; Abu-shqara, Elias; Yang, ChengXi Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6313 - 6317

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被引用次数: 46

摘要

Methods for the syntheses of bridge ketone and alcohol derivatives of methylene-bridged polyarenes from the parent hydrocarbons are described. The polyarenea investigated include 4H-cyclopenta [deflphenanthrene (la), fluorene (2a), 7H-bnzo [c] fluorene (b), 4H- cyclopenta [deflcbryaene (4a), llH-Benz [bc] aceanthrylene (Sa), lOH-indeno [1, 2, 7, 7a-bcd] pyrene (6a), l~-dibenm [bc,~ aceenthrylene (7a), 4H-fluoreno [4, 4e, 4b, 5abc] an~~ ne (h), ...