Bimetallic system for the synthesis of diorganyl selenides and sulfides, chiral β-seleno amines, and seleno-and thioesters

…, S Narayanaperumal, L Dornelles, OED Rodrigues…

文献索引：Gul, Kashif; Narayanaperumal, Senthil; Dornelles, Luciano; Rodrigues, Oscar E.D.; Braga, Antonio Luiz Tetrahedron Letters, 2011 , vol. 52, # 28 p. 3592 - 3596

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被引用次数: 17

摘要

Abstract The bimetallic reagent Sn (II)/Cu (II) in [bmim] BF 4 was efficiently used for the cleavage of diaryl diselenides and disulfides and reacts with a variety of organic substrates, such as organic halides, acid chlorides, and β-amino mesylates affording the diorganyl selenides and sulfides within very short reaction times, under mild conditions and with excellent yields, using BMIM-BF 4 as a reusable solvent.