Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

…, EJ Bush, IF McConvey, S Saubern, JH Ryan…

文献索引：Lee, Jin-Kyun; Fuchter, Matthew J.; Williamson, Rachel M.; Leeke, Gary A.; Bush, Edward J.; McConvey, Ian F.; Saubern, Simon; Ryan, John H.; Holmes, Andrew B. Chemical Communications, 2008 , # 39 p. 4780 - 4782

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被引用次数: 16

摘要

A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride- mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.