Novel thiophene-based cycloruthenated compounds: synthesis, characterization, and reactivity

L Cuesta, I Maluenda, T Soler, R Navarro…

文献索引：Cuesta, Luciano; Maluenda, Irene; Soler, Tatiana; Navarro, Rafael; Urriolabeitia, Esteban P. Inorganic Chemistry, 2011 , vol. 50, # 1 p. 37 - 45

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被引用次数: 10

摘要

A series of thiophene-based ruthenacycles were synthesized straightforwardly, employing imine units as directing groups. The cyclometalation event can be oriented to the heterocycle or to the aryl moiety as a function of the endo effect. These novel complexes react with I2, generating functionalized thiophenes.