Evidence for a Morin type intramolecular cyclization of an alkene with a phenylsulfenic acid group in neutral aqueous solution

K Keerthi, S Sivaramakrishnan…

文献索引：Sivaramakrishnan, Santhosh; Keerthi, Kripa; Gates, Kent S. Journal of the American Chemical Society, 2005 , vol. 127, # 31 p. 10830 - 10831

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被引用次数: 2

摘要

Sulfenic acids (RSOH) are among the most common sulfur-centered reactive intermediates generated in biological systems. Given the biological occurrence of sulfenic acids, it is important to explore the reactivity of these intermediates under physiological conditions. The Morin rearrangement is a synthetic process developed for the conversion of penicillin derivatives into cephalosporins that proceeds via nucleophilic attack of an alkene on a ...