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Reactions and spectral properties of 2-amino-3-cyano-4, 5-disubstituted furane derivatives

J Prousek, A Jurášek, J Kováč

文献索引:Prousek, Josef; Jurasek, Adolf; Kovac, Jaroslav Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 5 p. 1581 - 1588

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被引用次数: 13

摘要

Abstract Propanedinitrile reacts with acyloins I-III to give 2-amino-3-cyano-4, 5-disubstituted furanes IV-VI; the latter react with formamide to give 4-amino-5, 6-disubstituted furo [2, 3-b] oyrimidines VII-IX. The derivative IV reacts with acetanhydride to 2-acetylamino-3-cyano-4, 5- di (2-furyl) furane (X), and aminofurane VI reacts with acetanhydride to give 2-(N, N- diacetylamino)-3-cyano-4, 5-diphenylfurane (XI). With aldehydes the aminofuranes IV-VI ...