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Screw sense selective polymerization of achiral isocyanides catalyzed by optically active nickel (II) complexes

PCJ Kamer, RJM Nolte, W Drenth

文献索引:Kamer, Paul C. J.; Nolte, Roeland J. M.; Drenth, Wiendelt Journal of the American Chemical Society, 1988 , vol. 110, # 20 p. 6818 - 6825

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被引用次数: 167

摘要

Results The isocyanides used in this study were synthesized from the corresponding amines according to the general procedure shown in Scheme I. The amines la-d and If were N- formylated with an excess of ethyl formate. 16 The anilines le, lg, li, 11, and lo were treated with formic acid/acetic anhydride to give the N-formylated products. Anilines lb, lj, lk, lm, In, and lp were formylated with formic acid in toluene." Isocyanides 3a-d were synthesized ...

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