Tetrahedron

Photoinduced reactions—XLVI: Photochemistry of hindered nitrobenzene derivatives

Y Kjtaura, T Matsuura

文献索引：Kitaura,Y.; Matsuura,T. Tetrahedron, 1971 , vol. 27, p. 1583 - 1595

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被引用次数: 20

摘要

The photochemistry of various types of hindered nitrobenzenes, inparticular 2, 6-diakyl- substituted nitrobenzenes, has been investigated. Depending on steric factors, two types of reaction were observed. One, the photochemical reduction and nitro-nitrite rearrangement depending on the solvent employed, and the other, the intramolecular oxygen transfer reaction involving α-and β-carbon atom attack of an alkyl side chain. The former type ...