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The Journal of Organic Chemistry

Demjanov Rearrangement of 1-Methylcyclohexanemethylamine

R Kotani

文献索引:Kotani,R. Journal of Organic Chemistry, 1965 , vol. 30, p. 350 - 354

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被引用次数: 26

摘要

I-Methylcyclohexanemethylamine has been prepared and characterized. The Demjanov rearrangement of this amine has been investigated, yielding aa products l- methylcycloheptano1 (67%), 1-ethylcyclohexanol (ll%), 1-methylcycloheptene (3.8%), methylenecycloheptane (1.3%), 1-ethylcyclohexene (2.8%), and ethylidenecyclohexane (0.25%). The composition of the product alcohols and cycloalkenes were determined by ...