The Journal of Organic Chemistry

Homolytic reactions of phenyl tribromomethyl sulfone and olefins

DL Fields Jr, H Shechter

文献索引：Fields, D. L.; Shechter, H. Journal of Organic Chemistry, 1986 , vol. 51, # 17 p. 3369 - 3371

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被引用次数: 15

摘要

3 sulfony1) methylene (3), addition of 1 to varied olefins was observed.'Reactions of 1 with terminal olefins 4 (1) at reflux under nitrogen in benzene or (2) upon irradiation (400-W mercury lamp) in benzene at 20-25" C have now been found to involve directed homolytic addition to give the corresponding phenyl 1, 1, 3-tribromoalkyl sulfones (5, eq 2). Thus 2- methyl-l-butene (4a), l-octene (4b), and