Journal of organometallic chemistry

Highly regioselective hydroformylation of internal, functionalized olefins applying Pt/Sn complexes with large bite angle diphosphines

P Meessen, D Vogt, W Keim

文献索引：Meessen, Patric; Vogt, Dieter; Keim, Wilhelm Journal of Organometallic Chemistry, 1998 , vol. 551, # 1-2 p. 165 - 170

全文：HTML全文

被引用次数: 42

摘要

The regioselective hydroformylation of methyl 3-pentenoate (M3P) leading to linear 5-formyl methyl pentanoate (3-FMP) was studied. For this purpose Pt/Sn catalyst systems were modified by diphosphine ligands derived from heteroaromatic xanthene-type hydrocarbons. These xantphos ligands possess a large bite angle combined with a rigid backbone. The (P∩ P) PtCl2 catalyst precursor complexes were prepared and characterized by 1H-and ...

详细

624-24-8

戊酸甲酯

详细

New Phosphane Based on a β??Cyclodextrin, Exhibiting a Solve...

[Machut-Binkowski, Cecile; Legrand, Francois-Xavier; Azaroual, Nathalie; Tilloy, Sebastien; Monflier, Eric Chemistry - A European Journal, 2010 , vol. 16, # 33 p. 10195 - 10201]

An efficient route to functionalized dienes for decalin synt...

[Benbow, John W.; Katoch, Reeti; Martinez, Bonnie L.; Shetzline, Steven B. Tetrahedron Letters, 1997 , vol. 38, # 23 p. 4017 - 4020]

Stereocontrol in organic synthesis using silicon-containing ...

[Archibald, Sarah C.; Barden, David J.; Bazin, Jerome F.Y.; Fleming, Ian; Foster, Colin F.; Mandal, Ajay K.; Mandal, Amit K.; Parker, David; Takaki, Ken; Ware, Anne C.; Williams, Anne R.B.; Zwicky, Anna B. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 7 p. 1051 - 1064]

Rearrangements of 2-pyrones and pyran-2-thiones involving 1,...

[Pirkle,W.H.; Turner,W.V. Journal of Organic Chemistry, 1975 , vol. 40, # 11 p. 1617 - 1620]