Tetrahedron

Organic synthesis by means of noble metal complexes—XCIV: Palladium catalyzed hydrosilylation of monoenes and conjugated dienes

J Tsuji, M Hara, K Ohno

文献索引：Tsuji,J. et al. Tetrahedron, 1974 , vol. 30, p. 2143 - 2146

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被引用次数: 88

摘要

Palladium compounds and metallic palladium combined with phosphine are active catalysts of selective hydrosilylation of terminal olefins. Butadiene and trichlorosilane give a 1: 1 adduct and trimethylsilane affords a 1: 2 adduct. Special features of the palladium catalyzed hydrosilylation reactions are presented.