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Tetrahedron

Aromatic annulation with naphtho [1, 8-de]-1, 3-dithiin carbocations

SA Gamage, RAJ Smith

文献索引:Gamage, Swarna A.; Smith, Robin A. J. Tetrahedron, 1990 , vol. 46, # 6 p. 2111 - 2128

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被引用次数: 21

摘要

The title carbocations have been produced by the reaction of silver trifluoromethanesulfonate with mixed orthothioesters. Intramolecular aromatic electrophilic substitution (annulation) of the cationic intermediates proceeds readily and provides an efficient, chemoselective route for appending six-membered rings to nonactivated aromatic systems.