Tetrahedron letters

Reaction of tetracarbonyl (π-allyl) manganese with carbon nucleophiles

WS Vaughan, HH Gu, KF McDaniel

文献索引：Vaughan, William S.; Gu, Henry H.; McDaniel, Keith F. Tetrahedron Letters, 1997 , vol. 38, # 11 p. 1885 - 1888

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被引用次数: 11

摘要

Nucleophilic attack on tetracarbonyl (π-allyl) manganese takes place at the terminus of the π- system, generating allylated products in 44–95% yield after oxidation. Stabilized nucleophiles (pKa 12–20) give mainly bis allylation whereas nonstabilized nucleophiles (pKa 25–35) give mono allylation.