A new transformation of amines to carbonyl compounds

…, Y Matsumura, S Kashimura

文献索引：Shono, Tatsuya; Matsumura, Yoshihiro; Kashimura, Shigenori Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3338 - 3340

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被引用次数: 10

摘要

Interestingly, the electrochemical oxidation of carbamates 5 bearing a secondary alkyl group in methanol containing tetraethylammonium p-toluenesulfonate (TEATS) as a supporting electrolyte gave directly dimethyl ketals 6 in good yields (Scheme 11). Although there is no concrete evidence to support the intervention of a-methoxylated carbamates 7, the dimethyl ketals 6 were probably formed by methanolysis of the a-methoxy carbamates 7 catalyzed ...