Desilylative Pummerer-like rearrangement of α-trimethylsilyl-substituted sulphoxides and sulphides: formation of α-acyloxy and α-halogeno sulphides

…, H Nakatani, K Maruyama, K Minami, M Ikeda

文献索引：Ishibashi, Hiroyuki; Nakatani, Hiroshi; Maruyama, Kazumi; Minami, Kenjiro; Ikeda, Masazumi Journal of the Chemical Society, Chemical Communications, 1987 , # 19 p. 1443 - 1445

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被引用次数: 3

摘要

α-Trimethylsilyl-substituted sulphoxides and sulphides undergo rearrangement with loss of the silyl group when treated respectively with trifluoroacetic anhydride and with N- halogenosuccinimide in the presence of trifluoroacetic acid, giving α-acyloxy sulphides and α-halogeno sulphides.