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Chemische Berichte

Nucleophile Substitution von Nitrit in Nitrobenzolen, Nitrobiphenylen und Nitronaphthalinen

F Effenberger, M Koch, W Streicher

文献索引:Effenberger, Franz; Koch, Markus; Streicher, Willi Chemische Berichte, 1991 , vol. 124, # 1 p. 163 - 173

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被引用次数: 43

摘要

Aromatic compounds, accessible only by multistep procedures, can be synthesized easily by nucleophilic substitution of nitrite in nitrobenzenes, nitrobiphenyls, and nitronaphthalenes. Thus, meta-substituted phenols 3.4, and 7 are obtained from 1, 3-dinitrobenzene (1) and meta-substituted nitrobenzenes 6, as well as 3, 5-disubstituted phenols 10 and 5-substituted resorcinol derivatives 11 from 3, 5-disubstituted nitrobenzenes 9. The unsymmetrically ...