The Journal of Organic Chemistry

Chemistry of N-halamines. XII. Amination of alkyl halides with trichloramine-aluminum chloride

P Kovacic, MK Lowery

文献索引：Kovacic,P.; Lowery,M.K. Journal of Organic Chemistry, 1969 , vol. 34, p. 911 - 917

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被引用次数: 16

摘要

Recent reports from this laboratory have revealed that the direct amination of aromatic compounds with N-halamines under Friedel-Crafts conditions leads to products of unusual orientation. When monoalkylbenzenes were treated with trichloramine and aluminum chloride or aluminum bromide, the corresponding malkylanilines were formed."* The proposed mech-