Electronic Effects on C—O—C Ether Bonds in 3-Aryloxy Derivatives of Benzisothiazole 1, 1-Dioxides: Rapid Ethanolysis of 3-(4-Nitrophenoxy)-1, 2-benzisothiazole 1, …

…, PM Goncalves, RAW Johnstone

文献索引：Brigas; Goncalves; Johnstone Acta Crystallographica, Section C: Crystal Structure Communications, 1998 , vol. 54, # pt 2 p. 251 - 253

全文：HTML全文

被引用次数: 4

摘要

The bond lengths in the central C—O—C ether linkage of title compound (1), C13H8N2O5S, are comparable with those found in earlier work on similar compounds. However,(1) was found to undergo very easy solvolysis with ethanol to give (2), C9H9NO3S, for which a structure was also determined, but 3-(4-methoxyphenoxy)-1, 2-benzisothiazole 1, 1- dioxide,(3), did not hydrolyse under the same conditions. If ground-state structures are ...