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Electrooxidative Cyclization of Hydroxyamino Compounds Possessing a Benzyl Group

M Okimoto, K Ohashi, H Yamamori, S Nishikawa…

文献索引:Okimoto, Mitsuhiro; Ohashi, Kousuke; Yamamori, Haruki; Nishikawa, Shinnosuke; Hoshi, Masayuki; Yoshida, Takashi Synthesis, 2012 , vol. 44, # 9 p. 1315 - 1322

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被引用次数: 1

摘要

Abstract Several novel 2-aryl-1, 3-oxazinane and 2-aryl-1, 3-oxazolidine derivatives were synthesized from N-benzyl-2-piperidineethanols and N-benzyl-2-piperidinemethanols, respectively, by using electrooxidative methods in methanol. For these reactions, the yields of the corresponding cyclized compounds were significantly increased by using catalytic amounts of iodide ions. In contrast, 3-dialkylamino-1-phenylpropanols afforded the ...