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Krypton bis [pentafluoro-oxotellurate (VI)], Kr (OTeF 5) 2, the first example of a Kr–O bond

JCP Sanders, GJ Schrobilgen

文献索引:Sanders, Jeremy C. P.; Schrobilgen, Gary J. Journal of the Chemical Society, Chemical Communications, 1989 , # 20 p. 1576 - 1578

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被引用次数: 23

摘要

Krypton bis [pentafluoro-oxotellurate ()] provides the first example of a species containing a krypton–oxygen bond and has been prepared by the reaction of KrF with natural abundance and O-enriched B (OTeF) at–90 to–112° C in SOCIF solvent; characterization of the thermally unstable Kr (OTeF) and its decomposition pr