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Tetrahedron

Integrating chemosensors for amine-containing compounds into cross-linked dendritic hosts

E Mertz, SL Elmer, AM Balija, SC Zimmerman

文献索引:Mertz, Eric; Elmer, Stephanie L.; Balija, Amy M.; Zimmerman, Steven C. Tetrahedron, 2004 , vol. 60, # 49 p. 11191 - 11204

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被引用次数: 24

摘要

Trifluoroacetylazo dye, a known chemosensor for amines, has been integrated into cross- linked dendrimer hosts. Thus, boronic acid was linked to iododye via a Suzuki coupling reaction. In situ deprotection and alkylation with dendrons and, containing 8 homoallyl or allyl ether groups, respectively, afforded dendrons and with chemosensor units at their focal point. Conversion of () to the bis-imine of butane 1, 4-diamine, extensive cross-linking via ...