前往化源商城

举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Asymmetric Total Synthesis of Taxol\ R

T Mukaiyama, I Shiina, H Iwadare…

文献索引：Mukaiyama, Teruaki; Shiina, Isamu; Iwadare, Hayato; Saitoh, Masahiro; Nishimura, Toshihiro; Ohkawa, Naoto; Sakoh, Hiroki; Nishimura, Koji; Tani, Yu-Ichirou; Hasegawa, Masatoshi; Yamada, Koji; Saitoh, Katsuyuki Chemistry - A European Journal, 1999 , vol. 5, # 1 p. 121 - 161

全文：HTML全文

被引用次数: 263

摘要

Abstract A new method for the total asymmetric synthesis of antitumor agent Taxol is described. Baccatin III, a complex carbon framework, is synthesized by way of B to BC to ABC ring construction. Further, a method of forming Taxol from baccatin III and a β-amino acid is also demonstrated.

4-bromo-pent-4-enoic acid ethyl ester结构式

4-bromo-pent-4-...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

2-bromo-5-(triethylsilyloxy)pentene结构式

2-bromo-5-(trie...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(2R,3R,5R,6S,7S,8S)-2,6-Dibenzyloxy-3-(tert-butyldimethylsiloxy)-5-(p-methoxybenzyloxy)-4,4,8-trimethyl-7-{1-[3-(triethylsiloxy)propyl]vinyl}cyclooctanone结构式

(2R,3R,5R,6S,7S...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

三乙基氯硅烷结构式

三乙基氯硅烷

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

1,2-O,O-Carbonyl-7,13-O,O-bis(triethylsilyl)-4-deacetyl-2-debenzoylbaccatin III结构式

1,2-O,O-Carbony...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aS,6R,9S,11S,12S,12aS)-1-Bromomethyl-11,12-(carbonyldioxy)-4a,8,13,13-tetramethyl-5-oxo-4,9-bis(triethylsiloxy)-3,4,4a,5,6,9,10,11,12,12a-decahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aS,6R,9S,1...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aS,6R,9S,11S,12S,12aR)-11,12-(Carbonyldioxy)-4a,8,13,13-tetramethyl-1-methylene-5-oxo-4,9-bis(triethylsiloxy)-1,2,3,4,4a,5,6,9,10,11,12,12a-dodecahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aS,6R,9S,1...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(1S,4aR,5S,6S,9R,10R,11S,12S,12aS)-1,12-(Isopropylidenedioxy)-9,12a,13,13-tetramethyl-4-methylenetetradecahydro-6,10-methanobenzocyclodecene-5,6,9,10,11-pentaol结构式

(1S,4aR,5S,6S,9...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-11,12-(Carbonyldioxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-5,7,8-triol结构式

(4S,4aS,5S,6S,7...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aS,6R,11S,12S,12aR)-11,12-(Carbonyldioxy)-4a,8,13,13-tetramethyl-1-methylene-5-oxo-4-triethylsiloxy-1,2,3,4,4a,5,6,9,10,11,12,12a-dodecahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aS,6R,11S,...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aR,5S,6S,7R,8R,11S,12S,12aR)-11,12-(Carbonyldioxy)-5,7,8-trihydroxy-4a,8,13,13-tetramethyl-1-methylene-4-(triethylsiloxy)tetradecahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aR,5S,6S,7...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(1R,2S,5R,6S,7S,8S,9S)-2,6-Dibenzyloxy-5-(tert-butyldimethylsiloxy)-7,9-(isopropylidenedioxy)-4,4,8-trimethyl-12-methylenebicyclo[6.4.0]dodecan-3-one结构式

(1R,2S,5R,6S,7S...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(tert-butyldimethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(1S,2S,3S,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(3-butenyl)-6-(tert-butyldimethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecan-4-one结构式

(1S,2S,3S,6S,7S...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(cyclohexyldimethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(1S,2S,3S,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(tert-butyldimethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylene-6-(3-oxobutyl)bicyclo[6.4.0]dodecan-4-one结构式

(1S,2S,3S,6S,7S...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy-1α-(p-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans-bicyclo[6.4.0]dodecan-9-one结构式

2α,10β-dibenzyl...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(1S,2S,3S,4R,6R,7S,8R,12S)-3,7-Dibenzyloxy-4-(tert-butyldimethylsiloxy)-2,12-(isopropylidenedioxy)-6-(p-methoxybenzyloxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecane结构式

(1S,2S,3S,4R,6R...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(1S,2S,3R,4R,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(3-butenyl)-6-(dicyclohexylmethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecan-4-ol结构式

(1S,2S,3R,4R,6S...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(dicyclohexylmethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

(1S,2S,3S,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(dicyclohexylmethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylene-6-(3-oxobutyl)bicyclo[6.4.0]dodecan-4-one结构式

(1S,2S,3S,6S,7S...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

未登录结构式

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

4-bromopent-4-en-1-ol结构式

4-bromopent-4-e...

~%

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

2',3'-O,N-[(S)-(p-Methoxybenzylidene)]paclitaxel结构式

2',3'-O,N-[(S)-...

~94%

紫杉醇结构式

4-bromopent-4-en-1-ol结构式

4-bromopent-4-e...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

4-bromo-pent-4-enoic acid ethyl ester结构式

4-bromo-pent-4-...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

2-bromo-5-(triethylsilyloxy)pentene结构式

2-bromo-5-(trie...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(1R,2S,5R,6S,7S,8S,9S)-2,6-Dibenzyloxy-5-(tert-butyldimethylsiloxy)-7,9-(isopropylidenedioxy)-4,4,8-trimethyl-12-methylenebicyclo[6.4.0]dodecan-3-one结构式

(1R,2S,5R,6S,7S...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy-1α-(p-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans-bicyclo[6.4.0]dodecan-9-one结构式

2α,10β-dibenzyl...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(1S,2S,3S,4R,6R,7S,8R,12S)-3,7-Dibenzyloxy-4-(tert-butyldimethylsiloxy)-2,12-(isopropylidenedioxy)-6-(p-methoxybenzyloxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecane结构式

(1S,2S,3S,4R,6R...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(2R,3R,5R,6S,7S,8S)-2,6-Dibenzyloxy-3-(tert-butyldimethylsiloxy)-5-(p-methoxybenzyloxy)-4,4,8-trimethyl-7-{1-[3-(triethylsiloxy)propyl]vinyl}cyclooctanone结构式

(2R,3R,5R,6S,7S...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(1S,4aR,5S,6S,9R,10R,11S,12S,12aS)-1,12-(Isopropylidenedioxy)-9,12a,13,13-tetramethyl-4-methylenetetradecahydro-6,10-methanobenzocyclodecene-5,6,9,10,11-pentaol结构式

(1S,4aR,5S,6S,9...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-11,12-(Carbonyldioxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-5,7,8-triol结构式

(4S,4aS,5S,6S,7...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aR,5S,6S,7R,8R,11S,12S,12aR)-11,12-(Carbonyldioxy)-5,7,8-trihydroxy-4a,8,13,13-tetramethyl-1-methylene-4-(triethylsiloxy)tetradecahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aR,5S,6S,7...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(cyclohexyldimethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(1S,2S,3R,4R,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(3-butenyl)-6-(dicyclohexylmethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecan-4-ol结构式

(1S,2S,3R,4R,6S...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(dicyclohexylmethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(1S,2S,3S,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(dicyclohexylmethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylene-6-(3-oxobutyl)bicyclo[6.4.0]dodecan-4-one结构式

(1S,2S,3S,6S,7S...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

巴卡丁III结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

7-O-(三乙基硅烷)巴卡汀III结构式

7-O-(三乙基硅烷)巴卡汀III

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aS,6R,9S,11S,12S,12aR)-11,12-(Carbonyldioxy)-4a,8,13,13-tetramethyl-1-methylene-5-oxo-4,9-bis(triethylsiloxy)-1,2,3,4,4a,5,6,9,10,11,12,12a-dodecahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aS,6R,9S,1...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aS,6R,11S,12S,12aR)-11,12-(Carbonyldioxy)-4a,8,13,13-tetramethyl-1-methylene-5-oxo-4-triethylsiloxy-1,2,3,4,4a,5,6,9,10,11,12,12a-dodecahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aS,6R,11S,...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(tert-butyldimethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(1S,2S,3S,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(3-butenyl)-6-(tert-butyldimethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecan-4-one结构式

(1S,2S,3S,6S,7S...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(1S,2S,3S,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(tert-butyldimethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylene-6-(3-oxobutyl)bicyclo[6.4.0]dodecan-4-one结构式

(1S,2S,3S,6S,7S...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

三乙基氯硅烷结构式

三乙基氯硅烷

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

7,13-双-O-(三乙基甲硅烷基)浆果赤霉素III结构式

7,13-双-O-(三乙基甲硅...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

(4S,4aS,6R,9S,11S,12S,12aS)-1-Bromomethyl-11,12-(carbonyldioxy)-4a,8,13,13-tetramethyl-5-oxo-4,9-bis(triethylsiloxy)-3,4,4a,5,6,9,10,11,12,12a-decahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aS,6R,9S,1...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

1,2-O,O-Carbonyl-7,13-O,O-bis(triethylsilyl)-4-deacetyl-2-debenzoylbaccatin III结构式

1,2-O,O-Carbony...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

未登录结构式

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

1,2-O,O-Carbonyl-7,13-O,O-bis(triethylsilyl)-2-debenzoylbaccatin III结构式

1,2-O,O-Carbony...

~%

7-O-(三乙基甲硅烷基)紫杉醇结构式

7-O-(三乙基甲硅烷基)紫杉醇

2,2-二甲基-3-羟基丙酸甲酯结构式

2,2-二甲基-3-羟基丙酸甲酯

~87%

2,2-二甲基-3-氧代丙酸甲酯结构式

2,2-二甲基-3-氧代丙酸甲酯

甲醇结构式

苄氧乙酸结构式

~97%

苄氧乙酸甲酯结构式

苄氧乙酸甲酯

Methyl (4S,5R)-3-benzoyl-2,2-dimethyl-4-phenyl-1,3-oxazolidine-5-carboxylate结构式

Methyl (4S,5R)-...

~86%

(4S,5R)-3-苯甲酰基-2,2-二甲基-4-苯基氧氮杂环戊烷-5-甲酸结构式

(4S,5R)-3-苯甲酰基-...

(1S,4aR,5S,6S,9R,10R,11S,12S,12aS)-1,12-(Isopropylidenedioxy)-9,12a,13,13-tetramethyl-4-methylenetetradecahydro-6,10-methanobenzocyclodecene-5,6,9,10,11-pentaol结构式

(1S,4aR,5S,6S,9...

~%

巴卡丁III结构式

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-11,12-(Carbonyldioxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-5,7,8-triol结构式

(4S,4aS,5S,6S,7...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

(4S,4aR,5S,6S,7R,8R,11S,12S,12aR)-11,12-(Carbonyldioxy)-5,7,8-trihydroxy-4a,8,13,13-tetramethyl-1-methylene-4-(triethylsiloxy)tetradecahydro-7,11-methanobenzocyclodecen-6-yl acetate结构式

(4S,4aR,5S,6S,7...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

(1R,2S,5R,6S,7S,8S,9S)-2,6-Dibenzyloxy-5-(tert-butyldimethylsiloxy)-7,9-(isopropylidenedioxy)-4,4,8-trimethyl-12-methylenebicyclo[6.4.0]dodecan-3-one结构式

(1R,2S,5R,6S,7S...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(cyclohexyldimethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

巴卡丁III结构式

2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy-1α-(p-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans-bicyclo[6.4.0]dodecan-9-one结构式

2α,10β-dibenzyl...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

(1S,2S,3S,4R,6R,7S,8R,12S)-3,7-Dibenzyloxy-4-(tert-butyldimethylsiloxy)-2,12-(isopropylidenedioxy)-6-(p-methoxybenzyloxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecane结构式

(1S,2S,3S,4R,6R...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

(1S,2S,3R,4R,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(3-butenyl)-6-(dicyclohexylmethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylenebicyclo[6.4.0]dodecan-4-ol结构式

(1S,2S,3R,4R,6S...

~%

巴卡丁III结构式

(4S,4aS,5S,6S,7R,8R,11S,12S,12aR)-6,12-Dibenzyloxy-11-(dicyclohexylmethylsiloxy)-4,5-(isopropylidenedioxy)-4a,8,13,13-tetramethyl-1-methylenetetradecahydro-7,11-methanobenzocyclodecene-7,8-diol结构式

(4S,4aS,5S,6S,7...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

(1S,2S,3S,6S,7S,8R,12S)-3,7-Dibenzyloxy-6-(dicyclohexylmethylsiloxy)-2,12-(isopropylidenedioxy)-1,5,5-trimethyl-9-methylene-6-(3-oxobutyl)bicyclo[6.4.0]dodecan-4-one结构式

(1S,2S,3S,6S,7S...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

4-bromopent-4-en-1-ol结构式

4-bromopent-4-e...

~%

巴卡丁III结构式

4-bromo-pent-4-enoic acid ethyl ester结构式

4-bromo-pent-4-...

~%

巴卡丁III结构式

2-bromo-5-(triethylsilyloxy)pentene结构式

2-bromo-5-(trie...

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

未登录结构式

~%

巴卡丁III结构式

(2R,3R,5R,6S,7S,8S)-2,6-Dibenzyloxy-3-(tert-butyldimethylsiloxy)-5-(p-methoxybenzyloxy)-4,4,8-trimethyl-7-{1-[3-(triethylsiloxy)propyl]vinyl}cyclooctanone结构式

(2R,3R,5R,6S,7S...

~%

巴卡丁III结构式

氯乙酸结构式

苯甲醇结构式

~91%

苄氧乙酸结构式

甲醇结构式

未登录结构式

~83%

(2R,3S)-3-苯甲酰氨基-2-羟基-3-苯基丙酸甲酯结构式

(2R,3S)-3-苯甲酰氨基...

Enantioselective Synthesis of the Excitatory Amino Acid (1 S...

[Shiina, Isamu; Saitoh, Masahiro; Nishimura, Koji; Saitoh, Katsuyuki; Mukaiyama, Teruaki Chemistry Letters, 1996 , # 3 p. 223 - 224]

Enantioselective Synthesis of the Excitatory Amino Acid (1 S...

[Shiina, Isamu; Saitoh, Masahiro; Nishimura, Koji; Saitoh, Katsuyuki; Mukaiyama, Teruaki Chemistry Letters, 1996 , # 3 p. 223 - 224]

Enantioselective Synthesis of the Excitatory Amino Acid (1 S...

[Shiina, Isamu; Saitoh, Masahiro; Nishimura, Koji; Saitoh, Katsuyuki; Mukaiyama, Teruaki Chemistry Letters, 1996 , # 3 p. 223 - 224]

Enantioselective Synthesis of the Excitatory Amino Acid (1 S...

[Shiina, Isamu; Saitoh, Masahiro; Nishimura, Koji; Saitoh, Katsuyuki; Mukaiyama, Teruaki Chemistry Letters, 1996 , # 3 p. 223 - 224]

Enantioselective Synthesis of the Excitatory Amino Acid (1 S...

[Shiina, Isamu; Saitoh, Masahiro; Nishimura, Koji; Saitoh, Katsuyuki; Mukaiyama, Teruaki Chemistry Letters, 1996 , # 3 p. 223 - 224]