Palladium??Catalyzed α??Ketone Arylation under Mild Conditions

C Cao, L Wang, Z Cai, L Zhang, J Guo…

文献索引：Cao, Changsheng; Wang, Lingling; Cai, Zhengyuan; Zhang, Lingqiao; Guo, Jin; Pang, Guangsheng; Shi, Yanhui European Journal of Organic Chemistry, 2011 , # 8 p. 1570 - 1574

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被引用次数: 18

摘要

Abstract The α-arylation of ketones with aryl halides catalyzed by the easily prepared and air- stable palladium complex (SIPr) Pd (Py) Cl 2 (3) is described. Complex 3 displays high activity for a variety of aryl halides (activated, unactivated, and sterically hindered aryl halides) under mild conditions. Moreover, both aryl and alkyl ketones can be arylated. The α- arylation of some alkyl ketones can even be run at room temperature. The mono-or ...