Organic letters

Manganese (III)-mediated transformations of phloroglucinols: a formal oxidative [4+ 2] cycloaddition leading to bicyclo [2.2. 2] octadiones

B Mitasev, JA Porco Jr

文献索引：Mitasev, Branko; Porco Jr., John A. Organic Letters, 2009 , vol. 11, # 11 p. 2285 - 2288

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被引用次数: 35

摘要

Manganese (III)-mediated oxidative transformations of dearomatized phloroglucinol (1, 3, 5- trihydroxybenzene) derivatives are reported. A number of cyclization modes have been observed, including polycyclization to afford bicyclo [2.2. 2] octadiones via a formal oxidative radical [4+ 2] cycloaddition.