Chemiluminescence of secondary peroxy esters

BG Dixon, GB Schuster

文献索引：Dixon, Brian G.; Schuster, Gary B. Journal of the American Chemical Society, 1981 , vol. 103, # 11 p. 3068 - 3077

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被引用次数: 27

摘要

Abstract: The thermolysis of 1-phenylethyl peroxyacetate and a series of substituted 1- phenylethyl peroxybenzoates was investigated. Thermolysis in benzene gives acetophenone and the corresponding carboxylic acid. The study of the reaction kinetics and kinetic isotope effect indicates that the unimolecular thermolysis proceeds by homolysis of the oxygen-oxygen bond. Electronically excited states are formed in the thermolyses of ...