Journal of the American Chemical Society

Rates of Saponification of Substituted Ethyl 2-Naphthoates1

CC Price, RH Michel

文献索引：Price; Michel Journal of the American Chemical Society, 1952 , vol. 74, p. 3652,3653

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被引用次数: 18

摘要

The rates of saponification of ethyl 2-naphthoates and derivatives containing 6-and 7- methoxy1, 5-and 8-amino, 8-diinethylamino and 5-and 8-nitro groups have been measured in io?; aqueous dioxane, for most of the compounds at two temperatures. The dipole moment of ethyl 8-nitro-2-naphthoate can be adequately accounted for by assuming that the rotational conformation of the ester group is influenced by the electric field of the nitro ...