Journal of Organometallic Chemistry

The relative electron-releasing power of trimethylsilyl and tert-butyl groups

DRM Walton

文献索引：Walton,D.R.M. Journal of Organometallic Chemistry, 1965 , vol. 3, p. 438 - 441

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被引用次数: 0

摘要

Abstract The compounds m-and p-(Me 2 CCH 2) C 6 H 4 SiMe 3 have been synthesized, and the rates of their cleavage by aqueous-methanolic perchloric acid have been measured and compared with those of the corresponding m-and p-(Me 3 SiCH 2) C 6 H 4 SiMe 3 compounds. The results show that the inductive release of electrons to a saturated carbon atom is markedly greater for the Me 3 Si than for the Me 3 C group.