The Action of Elementary Fluorine upon Organic Compounds. XXVII. The Direct Fluorination of Fluorinated Aliphatic Dinitriles

BC Bishop, JB Hynes, LA Bigelow

文献索引：Bishop et al. Journal of the American Chemical Society, 1963 , vol. 85, p. 1606

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被引用次数: 11

摘要

CF3CFzCFz CFsNFz. NF2 and the final production of n-CkFgNF2. On the other hand, the original adduct might undergo cleavage with the formation of FCN and CF3CF2CF= N.. The latter would then undergo alkylation by CFzN= N. itself produced by the fluorination of FCN through the nitrene and azo dimer. 3 This would give first the isolated unsaturate CF3N= CFC? F~ and finally its saturated analog. Similar schemes may readily be set up for the ...