Quinone methide generation via photoinduced electron transfer

…, M Palumbo, M Di Antonio, M Freccero

文献索引：Percivalle, Claudia; La Rosa, Andrea; Verga, Daniela; Doria, Filippo; Mella, Mariella; Palumbo, Manlio; Di Antonio, Marco; Freccero, Mauro Journal of Organic Chemistry, 2011 , vol. 76, # 9 p. 3096 - 3106

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被引用次数: 27

摘要

Photochemical activation of water-soluble 1, 8-naphthalimide derivatives (NIs) as alkylating agents has been achieved by irradiation at 310 and 355 nm in aqueous acetonitrile. Reactivity in aqueous and neat acetonitrile has been extensively investigated by laser flash photolysis (LFP) at 355 nm, as well as by steady-state preparative irradiation at 310 nm in the presence of water, amines, thiols, and ethyl vinyl ether. Product distribution analysis ...