Chemistry Letters

A Novel, Simple and Cheap Source of Alkyl Radicals from Alcohols, Useful for Heteroaromatic Substitution.

…, F Fontana, E Lazzarini, F Minisci, G Pianese, L Zhao

文献索引：Coppa, Fausta; Fontana, Francesca; Lazzarini, Edoardo; Minisci, Francesco; Pianese, Giuseppe; Zhao, Lihua Chemistry Letters, 1992 , # 7 p. 1295 - 1298

全文：HTML全文

被引用次数: 9

摘要

Alkyl radicals were easily produced from secondary or tertiary alcohols in a cheap and simple way by silver-catalyzed decarboxylation of oxalic acid monoesters by S 2 O 8=. They were utilized for the alkylation of heteroaromatic bases in a two-phase system, with high yields and selectivity.