The Journal of Organic Chemistry

Photostimulated reaction of diphenylarsenide and diphenylstibide ions with haloaromatic compounds by the SRN1 mechanism. Electron transfer vs. bond breaking of …

RA Alonso, RA Rossi

文献索引：Alonso, Ruben A.; Rossi, Roberto A. Journal of Organic Chemistry, 1982 , vol. 47, # 1 p. 77 - 80

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被引用次数: 37

摘要

Photostimulated reactions of haloaromatic compounds with potassium diphenylarsenide and potassium diphenylstibide were studied in liquid ammonia. 1-Bromonaphthalene and 9- bromophenanthrene reacted with diphenylarsenide ion to give four products: triphenylarsine, diphenylarylarsine, phenyldiarylarsine, and triarylarsine (aryl= 1-naphthyl and 9-phenanthryl); with 2-chloroquinoline as substrate only the straightforward ...