Electrochemical reduction of carbon dioxide using iron–sulfur clusters as catalyst precursors

…, Y Mizobe, Y Matsumoto, Y Uchida, M Tezuka…

文献索引：Nakazawa, Makoto; Mizobe, Yasushi; Matsumoto, Yoichi; Uchida, Yasuzo; Tezuka, Meguru; Hidai, Masanobu Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 3 p. 809 - 814

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被引用次数: 32

摘要

The potential-current relationships of DMF solutions of a series of iron–sulfur compounds have revealed that in the presence of clusters [Fe 4 S 4 (SR) 4] 2−(R= PhCH 2 or Bu t) and [M 2 Fe 6 S 8 (SEt) 9] 3−(M= Mo or W) the electroreduction of CO 2 proceeds at the potential shifted by about 0.7 and 0.5 V, respectively, to the positive direction compared to the potential at which CO 2 is reduced without any catalyst. When controlled potential ...